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Campigliait

Bildbreite: 1 mm, Fundort: Temperino Mine, Campiglia Marittima, Livorno, Toskana, Italien

Richard De Nul

Contribution: thdun5 2010-06-24

Locality: Temperino Mine / Campiglia Marittima / Livorno, Provinz / Toskana (Toscana) / Italien

Collectors Summary

Color

hellblau

Streak color

bläulichweiß

Solubility

+++ Säuren

Crystal System

monoklin, C2

Chemism

Chemical formula

Mn²⁺Cu₄[(OH)₆|(SO₄)₂]·4H₂O

Chemical composition

Kupfer, Mangan, Sauerstoff, Schwefel, Wasserstoff

Unit weight: 675.3552479 u; Number of atoms in the formula: 39

Info

Empirical formula:

MnCu₄[(OH)₆(SO₄)₂]·4H₂O

Element	Symbol	Weight%	Atoms	Atoms%	Atom weight (u)	Sum weight (u)
Hydrogen	H	2.09	14	35.90	1.0079470	14.1112580
Oxygen	O	42.64	18	46.15	15.9994300	287.9897400
Sulfur	S	9.50	2	5.13	32.0655000	64.1310000
Manganese	Mn	8.13	1	2.56	54.9380499	54.9380499
Copper	Cu	37.64	4	10.26	63.5463000	254.1852000

Search for minerals with similar chemistry

Strunz 9th edition incl. updates

7.DD.30

7: Sulfate (Selenate, Tellurate, Chromate, Molybdate, Wolframate)
D: Sulfate (Selenate, etc.) mit weitere Anionen, mit H₂O
D: mit mittelgroßen Kationen; Lagen von kantenverknüpften Oktaedern
30:Devillin-Gruppe

Lapis Classification

VI/D.19-002

VI: SULFATE, CHROMATE, MOLYBDATE UND WOLFRAMATE
D: Wasserhaltige Sulfate, mit fremden Anionen
19: Mittelgroße und sehr große Kationen

Classification by Hölzel

7.DB.300

7: SULFATES CHROMATES MOLYBDATES WOLFRAMATES
D: Sulfates (+Anions +Water)
B: Langite-Group

Dana 8th edition

31.06.06.01

31: Hydrated Sulfates Containing Hydroxyl or Halogen
06: Hydrated Sulfates Containing Hydroxyl or Halogen where (A+ B++)5 (XO4)2 Zq·x(H2O)

IMA status

Anerkannt von der CNMNC

Mineral status

anerkanntes Mineral

Optical Properties

Color	hellblau
Streak color	bläulichweiß
max. Birefringence	0.070
	$Birefringence chart\! Campigliaite title=Birefringence chart Campigliaite$ Michel-Levy Color Chart viewed according to the maximum birefringence (at 30μm). Mineral color is not taken into account. Click on the image to enlarge or change thickness.
RI value α / ω / n	1.589
RI value β	1.645
RI value γ / ε	1.659
Ri mean	1.631
2V angle	Biaxial (-) 52°

Crystallography

Crystal System	monoklin
Class (H-M)	2
Space Group number	5
Space Group	C2
Cell parameters a (Å)	21.707
Cell parameters b (Å)	6.098
Cell parameters c (Å)	11.245
Cell parameters a/b or c/a	3.560
Cell parameters c/b	1.844
Cell parameters α	90°
Cell parameters β	100.30
Cell parameters γ	90°
Z	4
Volumne (Å³)	1464.506
X-Ray Powder Diffraction	10.68(100), 5.34(60), 3.56(40), 2.67(10)
	Calculated from d-spacing and intensity at 0.1541838 nm (Cu)

Crystals 3D

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Crystal Structure 3D

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Physical Properties

Density (g/cm³)	3.00 (gemessen)
	3.063 ( ρ calc. Mineralienatlas )
Instability	+++ Säuren

(Co-)Type locality

Italien /Toskana (Toscana)/Livorno, Provinz /Campiglia Marittima /Temperino Mine

Preface

Author (Name, Year)

Menchetti & Sabelli, 1982

References

Handbook of Mineralogy (Anthony et al.), 5 (2003), 109

Related minerals "Strunz Classification" (9. Edition) [Mineral | Chemical formula | Crystal system : Class (H-M) : Space Group | Indenture number]

Devilline	CaCu₄(SO₄)₂(OH)₆·3H₂O monoklin : 2/m : P2₁/c	7.DD.30
Serpierite	Ca(Cu,Zn)₄(SO₄)₂(OH)₆·3H₂O monoklin : 2/m : C2/c	7.DD.30
Campigliaite	Mn²⁺Cu₄[(OH)₆\|(SO₄)₂]·4H₂O monoklin : 2 : C2	7.DD.30
Edwardsite	Cu₃Cd₂(SO₄)₂(OH)₆·4H₂O monoklin : 2/m : P2₁/C	7.DD.30
Aldridgeite	(Cd,Ca)(Cu,Zn)₄(SO₄)₂(OH)₆·3H₂O monoklin : 2/m : C2/c	7.DD.30
Lautenthalite	PbCu₄²⁺(OH)₆(SO₄)₂·3H₂O monoklin : 2/m : P2₁/c	7.DD.30
Niedermayrite	CdCu₄[(OH)₆\|(SO₄)₂]·4H₂O monoklin : 2/m : P2₁/m	7.DD.30
Orthoserpierite	Ca(Cu,Zn)₄(SO₄)₂(OH)₆·3H₂O orthorhombisch : mm2 : Pca2₁	7.DD.30

Related minerals "Lapis Classification" [Mineral | Chemical formula | Crystal system : Class (H-M) : Space Group | Indenture number]

Campigliaite	Mn²⁺Cu₄[(OH)₆\|(SO₄)₂]·4H₂O monoklin : 2 : C2	VI/D.19-002
Edwardsite	Cu₃Cd₂(SO₄)₂(OH)₆·4H₂O monoklin : 2/m : P2₁/C	VI/D.19-004
Niedermayrite	CdCu₄[(OH)₆\|(SO₄)₂]·4H₂O monoklin : 2/m : P2₁/m	VI/D.19-005
Kobyashevite	Cu₅(SO₄)₂(OH)₆·4H₂O triklin : 1 : P1	VI/D.19-008
Devilline	CaCu₄(SO₄)₂(OH)₆·3H₂O monoklin : 2/m : P2₁/c	VI/D.19-010
Aldridgeite	(Cd,Ca)(Cu,Zn)₄(SO₄)₂(OH)₆·3H₂O monoklin : 2/m : C2/c	VI/D.19-015
Serpierite	Ca(Cu,Zn)₄(SO₄)₂(OH)₆·3H₂O monoklin : 2/m : C2/c	VI/D.19-020
Orthoserpierite	Ca(Cu,Zn)₄(SO₄)₂(OH)₆·3H₂O orthorhombisch : mm2 : Pca2₁	VI/D.19-030
Lautenthalite	PbCu₄²⁺(OH)₆(SO₄)₂·3H₂O monoklin : 2/m : P2₁/c	VI/D.19-032
'Arzrunite'	Cu₄Pb₂SO₄O₂Cl₆·4H₂O	VI/D.19-035
Tatarskite	Ca₆Mg₂(SO₄)₂(CO₃)₂Cl₄(OH)₄·7H₂O	VI/D.19-040

Related minerals "Hoelzel Classification" [Mineral | Chemical formula : Crystal system : Class (H-M) | Space Group | Indenture number]

Campigliaite	Mn²⁺Cu₄[(OH)₆\|(SO₄)₂]·4H₂O monoklin : 2 : C2	7.DB.300
Niedermayrite	CdCu₄[(OH)₆\|(SO₄)₂]·4H₂O monoklin : 2/m : P2₁/m	7.DB.310
Christelite	Zn₃Cu₂[(OH)₆\|(SO₄)₂]·4H₂O triklin : 1 : P1	7.DB.320
Kobyashevite	Cu₅(SO₄)₂(OH)₆·4H₂O triklin : 1 : P1	7.DB.325
Ktenasite	ZnCu₄(SO₄)₂(OH)₆·6H₂O monoklin : 2/m : P2₁/c	7.DB.340
Edwardsite	Cu₃Cd₂(SO₄)₂(OH)₆·4H₂O monoklin : 2/m : P2₁/C	7.DB.350

Related minerals "Dana 8. Classification" [Mineral | Chemical formula : Crystal system : Class (H-M) | Space Group | Indenture number]

Devilline	CaCu₄(SO₄)₂(OH)₆·3H₂O monoklin : 2/m : P2₁/c	31.06.01.01
Lautenthalite	PbCu₄²⁺(OH)₆(SO₄)₂·3H₂O monoklin : 2/m : P2₁/c	31.06.01.02
Serpierite	Ca(Cu,Zn)₄(SO₄)₂(OH)₆·3H₂O monoklin : 2/m : C2/c	31.06.02.01
Ktenasite	ZnCu₄(SO₄)₂(OH)₆·6H₂O monoklin : 2/m : P2₁/c	31.06.03.01
Christelite	Zn₃Cu₂[(OH)₆\|(SO₄)₂]·4H₂O triklin : 1 : P1	31.06.03.02
Peretaite	CaSb₄³⁺O₄(OH)₂(SO₄)₂·2H₂O monoklin : 2/m : C2/c	31.06.04.01
Campigliaite	Mn²⁺Cu₄[(OH)₆\|(SO₄)₂]·4H₂O monoklin : 2 : C2	31.06.06.01
Niedermayrite	CdCu₄[(OH)₆\|(SO₄)₂]·4H₂O monoklin : 2/m : P2₁/m	31.06.06.02
Orthoserpierite	Ca(Cu,Zn)₄(SO₄)₂(OH)₆·3H₂O orthorhombisch : mm2 : Pca2₁	31.06.07.01
Rabejacite	Ca_2[(UO₂)₄O₄(SO₄)₂](H₂O)₈ triklin : 1 : P1	31.06.08.01

Other languages

German	Campigliait
English	Campigliaite
French	Campigliaite
Spanish	Campigliaíta
Russian	Кампильяит

IMA Number

IMA 1981-001

Automatic Links to external internet sources (Responsibility is with the operator)

German pages	DeWikiPedia - search for: Campigliait Google-Bilder-Suche - search for: Campigliait Mineralogisch-Petrographisches-Institut Hamburg - search for: Campigliait
English pages	Mindat - search for: Campigliaite Webmineral - search for:Campigliaite Handbook-of-Mineralogy - search for: Campigliaite RRUFF - Raman, XRD and other mineral data - search for: Campigliaite RRUFF - References and PDF downloads - search for: Campigliaite American-Mineralogist-Crystal-Structure-Database - search for: Campigliaite Athena - search for: Campigliaite
Russian pages	Webmineral.ru - search for: Кампильяит

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