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Philipsburgite

Pictures (19 Images total)

Brochantit
Views (File:
1377685397
): 639
Brochantit
Kugelige grüne Kristalle, Vielkristallkugeln auf blauem Philipsburgit, BB = 3,8 mm, Fundort: Black Pine Mine, Philipsburg,Granite Co., Montana, USA
Copyright: Bebo; Contribution: Münchener Micromounter
Collection: Lithothek der Münchener Micromounter, Collection number: A028003, Donator: eschuhbauer
Location: USA/Montana/Granite Co./Philipsburg District/Black Pine Mine
Mineral: Brochantite, Philipsburgite
Image: 1377685397
Rating: 9 (votes: 1)
License: Usage for Mineralienatlas project only
Brochantit (SNr: A028003)

Kugelige grüne Kristalle, Vielkristallkugeln auf blauem Philipsburgit, BB = 3,8 mm, Fundort: Black Pine Mine, Philipsburg,Granite Co., Montana, USA
Collection: Lithothek der Münchener Micromounter
Copyright: Bebo
Contribution: Münchener Micromounter 2013-08-28
Locality: Black Pine Mine / Philipsburg District / Granite Co. / Montana / USA
Philipsburgit
Views (File:
1178811158
): 2230, Rating: 8.4
Philipsburgit
Bildbreite: 6 mm; Fundort: Grube Clara, Wolfach, Schwarzwald
Copyright: Stephan Wolfsried; Contribution: Hg
Location: Deutschland/Baden-Württemberg/Freiburg, Bezirk/Ortenaukreis/Oberwolfach/Grube Clara
Mineral: Philipsburgite
Image: 1178811158
Rating: 8.4 (votes: 5)
License: Usage for Mineralienatlas project only
Philipsburgit

Bildbreite: 6 mm; Fundort: Grube Clara, Wolfach, Schwarzwald
Copyright: Stephan Wolfsried
Contribution: Hg 2007-05-10
Locality: Grube Clara / Oberwolfach / Ortenaukreis / Freiburg, Bezirk / Baden-Württemberg / Deutschland
Philipsburgit
Views (File:
1327589443
): 1283
Philipsburgit
Größe: 1,26 mm; Fundort: Sa Duchessa, Oridda, Domusnovas, Carbonia-Iglesias, Sardinien, Italien
Copyright: Matteo Chinellato; Contribution: Hg
Collection: Domenico Preite
Location: Italien/Sardinien (Sardegna), Region/Sud Sardegna, Provinz/Iglesias/Domusnovas/Oridda/Sa Duchessa
Mineral: Philipsburgite
Image: 1327589443
Rating: 7.67 (votes: 3)
License: Usage for Mineralienatlas project only
Philipsburgit

Größe: 1,26 mm; Fundort: Sa Duchessa, Oridda, Domusnovas, Carbonia-Iglesias, Sardinien, Italien
Collection: Domenico Preite
Copyright: Matteo Chinellato
Contribution: Hg 2012-01-26
Locality: Sa Duchessa / Oridda / Domusnovas / Iglesias / Sud Sardegna, Provinz / Sardinien (Sardegna), Region / Italien
Philipsburgit
Views (File:
1587749942
): 376
Philipsburgit
FO: Grube Clara / Oberwolfach; BB 1,8 mm
Copyright: Halden-Joerg; Contribution: Halden-Joerg
Location: Deutschland/Baden-Württemberg/Freiburg, Bezirk/Ortenaukreis/Oberwolfach/Grube Clara
Mineral: Philipsburgite
Image: 1587749942
Rating: 7.5 (votes: 2)
License: Usage for Mineralienatlas project only
Philipsburgit

FO: Grube Clara / Oberwolfach; BB 1,8 mm
Copyright: Halden-Joerg
Contribution: Halden-Joerg 2020-04-24
Locality: Grube Clara / Oberwolfach / Ortenaukreis / Freiburg, Bezirk / Baden-Württemberg / Deutschland
Philipsburgit
Views (File:
1216410289
): 679
Philipsburgit
Middle pit, Gold Hill Mine, Tooele Co., Utah, USA
Copyright: Eddy van der Meersche; Contribution: eschuhbauer
Collection: Lithothek der Münchener Micromounter, Collection number: A026096, Donator: eschuhbauer
Location: USA/Utah/Tooele Co./Deep Creek Mts./Gold Hill District (Clifton District)/Gold Hill/Gold Hill Mine
Mineral: Philipsburgite
Image: 1216410289
Rating: 8 (votes: 1)
License: Creative Commons - Attribution (CC-BY) V.3.0
Philipsburgit (SNr: A026096)

Middle pit, Gold Hill Mine, Tooele Co., Utah, USA
Collection: Lithothek der Münchener Micromounter
Copyright: Eddy van der Meersche
Contribution: eschuhbauer 2008-07-18
Locality: Gold Hill Mine / Gold Hill / Gold Hill District (Clifton District) / Deep Creek Mts. / Tooele Co. / Utah / USA

You find additional specimen at the Geolitho Museum

Collectors Summary

Color smaragdgrün
Streak color hellgrün
Hardness (Mohs) 3.5
Solubility +++ Säuren
Crystal System monoklin, P21/c

Chemism

Chemical formula

Cu5Zn(AsO4)(PO4)(OH)6⋅H2O

Chemical composition

Arsen, Kupfer, Zink, Phosphor, Sauerstoff, Wasserstoff

Unit weight: 737.0912892 u; Number of atoms in the formula: 31

Info

Empirical formula:

Cu5Zn(AsO4)(PO4)(OH)6⋅H2O

Element

Symbol

Weight%

Atoms

Atoms%

Atom weight (u)

Sum weight (u)
Hydrogen

H

1.09

8

25.81

1.0079470

8.0635760
Oxygen

O

32.56

15

48.39

15.9994300

239.9914500
Phosphorus

P

4.20

1

3.23

30.9737612

30.9737612
Copper

Cu

43.11

5

16.13

63.5463000

317.7315000
Zinc

Zn

8.87

1

3.23

65.4094000

65.4094000
Arsenic

As

10.16

1

3.23

74.9216020

74.9216020

Analysis wt%

CuO : 46.30, ZnO : 18.20, P2O5 : 8.70, As2O5 : 16.30, H2O : 9.90 (Ref: Canadian Mineralogist 85)

Strunz 9th edition incl. updates

8.DA.35

8: Phosphate, Arsenate, Vanadate
D: Phosphate, mit weiteren Anionen, mit H2O
A: Mit kleinen (und gelegentlich größeren) [Kationen]
35:Kipushit-Gruppe

Lapis Classification

VII/D.19-020

VII: PHOSPHATE, ARSENATE UND VANADATE ("Phosphate" des Registers immer einschließlich isotyper Arsenate und Vanadate!)
D: Wasserhaltige Phosphate, mit fremden Anionen
19: Mittelgroße Kationen: Cu-Zn-Mn-Al-Fe

Classification by Hölzel

8.DB.310

8: PHOSPHATES ARSENATES VANADATES
D: Phosphates (+Anions +Water)
B: Valency: 2, C medium

Dana 8th edition

42.02.04.02

42: Hydrated Phosphates, etc., Containing Hydroxyl or Halogen
02: Hydrated Phosphates, etc., Containing Hydroxyl or Halogen where (AB)3 (XO4) Zq · x(H2O)
04: Kipushite Group

IMA status

Anerkannt von der CNMNC

Mineral status

anerkanntes Mineral

Optical Properties

Color

smaragdgrün

Streak color

hellgrün

Diaphaneity (Transparency)

transparent bis semitransparent

max. Birefringence

0.046
Birefringence chart\! Philipsburgite title=Birefringence chart Philipsburgite

Michel-Levy Color Chart viewed according to the maximum birefringence (at 30μm). Mineral color is not taken into account. Click on the image to enlarge or change thickness.

RI value α / ω / n

1.729

RI value β

1.774

RI value γ / ε

1.775

Ri mean

1.759

2V angle

Biaxial (-) 16°

Optical Data Luminescence

Luminescence

keine Fluoreszenz bekannt

Crystallography

Crystal System

monoklin

Class (H-M)

2/m

Space Group number

14

Space Group

P21/c

Cell parameters a (Å)

12.3095(9)

Cell parameters b (Å)

9.2276(3)

Cell parameters c (Å)

10.7195(3)

Cell parameters a/b or c/a

1.334

Cell parameters c/b

1.162

Cell parameters α

90°

Cell parameters β

97.137(7)°

Cell parameters γ

90°

Z

4

Volume (ų)

1208.163

Crystal structure

Sergey V. Krivovichev, Elena S. Zhitova, Rezeda M. Ismagilova, Andrey A. Zolotarev: Site-selective As–P substitution and hydrogen bonding in the crystal structure of philipsburgite, Cu5Zn((As,P)O4)2(OH)6•H2O . Physics and Chemistry of Minerals Volume 45, Issue 10 (2018) S. 917–923.

X-Ray Powder Diffraction

12.2(80),
6.21(40),
4.29(40),
4.05(90),
3.405(50),
2.666(60),
2.559(100),
1.534(60)
XRD chart Philipsburgite

Calculated from d-spacing and intensity at 0.1541838 nm (Cu)

Crystals 3D

Open larger view

Physical Properties

Hardness (Mohs)

3.5

VHN (Hardness Vickers)

130 (ungefähre Angabe abgeleitet aus der Mohshärte)

Density (g/cm³)

4.07

4.052 ( ρ calc. Mineralienatlas )

Instability

+++ Säuren

Chemical Properties and Tests

Justyna Ciesielczuk, Janusz Janeczek, Mateusz Dulski, Tomasz Krzykawski: Pseudomalachite–cornwallite and kipushite–philipsburgite solid solutions: chemical composition and Raman spectroscopy. Eur. J. Mineral. Vol. 28 (2016) S. 555-569.

(Co-)Type locality

(Co-)Type locality

USA/Montana/Granite Co./Philipsburg District/Black Pine Mine

Preface

Author (Name, Year)

Peacor & Dunn & Ramik & Sturman & Zeihen, 1985

References

IMA 20-G: Redefinition of philipsburgite - CNMNC Newsletter 60; Mineralogical Magazine, 85, https://doi.org/10.1180/mgm.2021.30

Rezeda M. Ismagilova; Branko Rieck; Anthony R. Kampf; Gerald Giester; Elena S. Zhitova, Christian L. Lengauer; Sergey V. Krivovichev; Andrey A. Zolotarev; Justyna Ciesielczuk; Julia A. Mikhailova; Dmitry I. Belakovsky; Vladimir N. Bocharov; Vladimir V. Shilovskikh; Natalia S. Vlasenko; Barbara P. Nash; Paul M. Adams: Goldhillite, Cu5Zn(AsO4)2(OH)6⋅H2O, a new mineral species, and redefinition of philipsburgite, Cu5Zn[(AsO4)(PO4)](OH)6⋅H2O, as an As–P ordered species. Mineralogical Magazine Vol. 86, Nr. 3 (2022) S. 436-446

Other languages

German

Philipsburgit

Spanish

Philipsburgita

French

Philipsburgite

English

Philipsburgite

CNMNC (IMA)-Number

IMA 1984-029

CNMNC symbol

Symbol

Pbu

Locations with GPS information

IDs

GUSID (Global unique identifier short form) ndCt8J0WREm_6TUy3q3Rkg
GUID (Global unique identifier) F0ADD09D-169D-4944-BFE9-3532DEADD192
Database ID 3027