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Stibiobetafite

Collectors Summary

Color dunkelbraun, schwarz braun
Streak color bräunlich weiß
Hardness (Mohs) 5
Cleavages fehlt
Crystal System kubisch, Fd3m

Additional information / Summary

Černý et al. (1979) definierte Stibiobetafit als das Sb3+ Analog von Betafit; Das Typmaterial hatte Nb + Ta > Ti Atome pro Formeleinheit und Ca ist das dominate Element der dominanten Valenz-Gruppe der A-Seite. Das Typmaterial wurde als Oxycalciopyrochlor bestimmt.

Chemism

Chem­ical formula

(Sb3+,Ca)2(Ti,Nb,Ta)2(O,OH)7

Chem­ical com­po­si­tion

Antimon, Calcium, Niob, Tantal, Titan, Sauerstoff, Wasserstoff

Unit weight: 465.81319845 u; Number of atoms in the formula: 12.75

Info

Empirical formula:

(Sb0.75Ca0.25)2(Ti0.6Nb0.3Ta0.1)2(O0.75(OH)0.25)7

Element

Symbol

Weight%

Atoms

Atoms%

Atom weight (u)

Sum weight (u)

Hydrogen

H

0.38

1.75

13.73

1.0079470

1.7639073

Oxygen

O

24.04

7

54.90

15.9994300

111.9960100

Calcium

Ca

4.30

0.5

3.92

40.0784000

20.0392000

Titanium

Ti

12.33

1.2

9.41

47.8671000

57.4405200

Niobium

Nb

11.97

0.6

4.71

92.9063820

55.7438292

Antimony

Sb

39.21

1.5

11.76

121.7601000

182.6401500

Tantalum

Ta

7.77

0.2

1.57

180.9479100

36.1895820

Anal­y­sis wt%

Nb2O5 : 21.60, Ta2O5 : 19.30, TiO2 : 16.50, Al2O3 : 0.49, Sb2O3 : 23.20, SnO : 2.90, FeO : 0.60, MnO : 0.60, CaO : 14.50, H2O : 0.44 (Ref: Canadian Mineralogist 79)

Strunz 9th edi­tion incl. updates

4.DH.15

4: Oxide, Hydroxide (Oxide, Hydroxide, V[5,6]-Vanadate, Arsenite, Antimonite, Bismutite, Sulfite, Selenite, Tellurite, Iodate)
D: Metall: Sauerstoff = 1:2 und vergleichbare
H: Mit großen (± mittelgroßen) [Kationen]; Lagen kantenverknüpfter Oktaeder
15:Pyrochlor-Gruppe

Clas­sifica­tion by Hölzel

4.CH.141

4: OXIDES
C: R2O3 Sesquioxides
H: Pyrochlore-Group, Nb-dominant on the B-site

Dana 8th edi­tion

08.02.03.04

08: Multiple Oxides with Nb, Ta, and Ti
02: Multiple Oxides with Nb, Ta, and Ti where (A)2 (B2O6) (O,OH,F)
03: Pyrochlore Group (Betafite Subgroup; 2(Ti)>(Ta+Nb)

IMA sta­tus

diskreditiert, Redifinition - The Canadian Mineralogist Vol. 48, pp. 673-698 (2010)

Min­eral sta­tus

Varietät

Var­i­ety / poly­type of

Pyrochlore group

Optical Properties

Color

dunkelbraun, schwarz braun

Streak color

bräunlich weiß

Diaphane­ity (Trans­parency)

durchscheinend bis opak

RI value α / ω / n

2.2

Ri mean

2.2

2V angle

Isotropisch

Crystallography

Crystal Sys­tem

kubisch

Class (H-M)

m3m

Space Group number

227

Space Group

Fd3m

Cell param­e­ters a (Å)

10.356

Cell param­e­ters b (Å)

-

Cell param­e­ters c (Å)

-

Cell param­e­ters a/b or c/a

1

Cell param­e­ters c/b

-

Cell param­e­ters α

90°

Cell param­e­ters β

90°

Cell param­e­ters γ

90°

Z

8

Volumne (ų)

1110.647

X-Ray Pow­der Diffrac­tion

6.05(10),
3.11(10),
2.992(100),
2.585(30),
1.830(40),
1.560(40),
1.494(10),
1.158(10)

XRD chart Stibiobetafite

Calculated from d-spacing and intensity at 0.1541838 nm (Cu)

Crystals 3D

Open larger view

Physical Properties

Hard­ness (Mohs)

5

Density (g/cm³)

5.3

5.571 ( ρ calc. Mineralienatlas )

Cleav­ages

fehlt

Preface

Author (Name, Year)

Cerny & Hawthorne & Laflamme & Hinthorne, 1979

Related minerals "Strunz Classification" (9. Edition) [Mineral | Chemical formula | Crystal system : Class (H-M) : Space Group | Indenture number]

'Betafite (of Hogarth 1977)' (Var.v. Pyrochlore supergroup)

(Ca,Na,U)2(Ti,Nb,Ta)2O6(OH)

kubisch : m3m : Fd3m

4.DH.15

Hydroplumboelsmoreite

(Pb,☐)2(W,Fe3+)2O6(H2O)

kubisch : m3m : Fd3m

4.DH.15

Fluornatrocoulsellite

CaNa3AlMg3F14

trigonal : 3m : R3m

4.DH.15

Hydroxymanganopyrochlore

(Mn,Th,Na,Ca,REE)2(Nb,Ti)2O6(OH)

kubisch : m3m : Fd3m

4.DH.15

'Alumotungstite' (Var.v. Hydrokenoelsmoreite)

(H2O,Ca)x(W,Al)2(O,OH)6·nH2O

4.DH.15

'Calciobetafite' (Var.v. Pyrochlore supergroup)

Ca2(Ti,Nb)2(O,OH)7

kubisch : m3m : Fd3m

4.DH.15

'Cesstibtantite' (Var.v. Pyrochlore supergroup)

(Cs,Na)SbTa4O12

kubisch : m3m : Fd3m

4.DH.15

'Ferritungstite' (Var.v. Hydrokenoelsmoreite)

(W6+,Fe3+)2(O,OH)6·n(H2O,K,Ca,Na)

kubisch : m3m : Fd3m

4.DH.15

Hydropyrochlore

(H2O,☐)2Nb2(O,OH)6(H2O)

kubisch : m3m : Fd3m

4.DH.15

'Plumbobetafite' (Var.v. Pyrochlore supergroup)

(Pb,U,Ca)(Ti,Nb)2O6(OH,F)

kubisch : m3m : Fd3m

4.DH.15

'Stibiobetafite' (Var.v. Pyrochlore group)

(Sb3+,Ca)2(Ti,Nb,Ta)2(O,OH)7

kubisch : m3m : Fd3m

4.DH.15

'Uranmicrolite' (Var.v. Microlite group)

(Ca,U)2(Ta,Nb)2O6(OH,F)

kubisch : m3m : Fd3m

4.DH.15

'Uranopyrochlore' (Var.v. Pyrochlore supergroup)

(Ca,U,Na,Ce)2(Nb,Ta)2(O,OH,F)7

kubisch : m3m : Fd3m

4.DH.15

'Bariomicrolite'

Ba(Ta,Nb)2(O,OH)7

kubisch : m3m : Fd3m

4.DH.15

'Bariopyrochlore' (Var.v. Pyrochlore supergroup)

(Ba,Sr)(Nb,Ti)2(O,OH)7

kubisch : m3m : Fd3m

4.DH.15

'Natrobistantite' (Var.v. Microlite group)

(Na,Cs)Bi(Ta,Nb,Sb)4O12

4.DH.15

'Plumbomicrolite' (Var.v. Microlite group)

(Pb,Na,Ca)2(Ta,Nb)2(O,OH)7

kubisch : m3m : Fd3m

4.DH.15

'Plumbopyrochlore' (Var.v. Pyrochlore group)

(Pb,Y,U,Ca)2-xNb2O6(OH)

kubisch : m3m : Fd3m

4.DH.15

'Stannomicrolite' (Var.v. Microlite group)

(Sn2+,Fe2+)(Ta,Nb,Sn4+)2(O,OH)7

kubisch : m3m : Fd3m

4.DH.15

'Stibiomicrolite' (Var.v. Microlite group)

(Sb,Ca,Na)2(Ta,Nb)2(O,OH)7

kubisch : m3m : Fd3m

4.DH.15

'Bismutomicrolite'

(Bi,Ca)(Ta,Nb)2O6(OH)

kubisch : m3m : Fd3m

4.DH.15

'Bismutopyrochlore' (Var.v. Pyrochlore supergroup)

(Bi,U,Ca,Pb)1+x(Nb,Ta)2O6(OH)·nH2O

kubisch : m3m : Fd3m

4.DH.15

Oxynatromicrolite

(Na,Ca,U)2(Ta,Nb)2O6(O,F)

kubisch : m3m : Fd3m

4.DH.15

'Yttrobetafite-(Y)' (Var.v. Pyrochlore supergroup)

(Y,U,Ce)2(Ti,Nb,Ta)2O6(OH)

amorph

4.DH.15

'Strontiopyrochlore' (Var.v. Pyrochlore group)

Sr0.6Nb2(O,OH)7

kubisch : m3m : Fd3m

4.DH.15

Cesiokenopyrochlore

☐Nb2(O,OH)6Cs1−x {x ∼ 0.20}

kubisch : m3m : Fd3m

4.DH.15

Hydrokenoelsmoreite

WO3·0.5H2O

kubisch : m3m : Fd3m

4.DH.15

Hydrokenomicrolite

(◻,H2O)2Ta2(O,OH)6(H2O)

kubisch : m3m : Fd3m

4.DH.15

Oxybismutomicrolite

(Bi1.33☐0.67)Σ2Ta2O6O

kubisch : m3m : Fd3m

4.DH.15

Oxycalciomicrolite

Ca2Ta2O7

kubisch : m3m : Fd3m

4.DH.15

Oxystannomicrolite

Sn2Ta2O6O

kubisch : m3m : Fd3m

4.DH.15

Oxystibiomicrolite

(Sb3+,Ca)2Ta2O6O

4.DH.15

'Yttropyrochlore-(Y)' (Var.v. Pyrochlore group)

(Y,Na,Ca,U)1-2(Nb,Ta,Ti)2(O,OH)7

4.DH.15

'Ceriopyrochlore-(Ce)' (Var.v. Pyrochlore supergroup)

(Ca,Ce,Y,Na)2(Nb,Ta)2(O,OH,F)7

kubisch : m3m : Fd3m

4.DH.15

Fluornatromicrolite

(Na,Ca,Bi)2(Ta,Nb)2O6F

kubisch : m3m : Fd3m

4.DH.15

Fluornatropyrochlore

(Na,Pb,Ca,REE,U)2Nb2O6F

kubisch : m3m : Fd3m

4.DH.15

Hydrokenopyrochlore

2Nb2O4(OH)2(H2O)

kubisch : m3m : Fd3m

4.DH.15

Hydroxyferroroméite

(Fe2+1.50.5)Sb5+2O6(OH)

kubisch : m3m : Fd3m

4.DH.15

Kenoplumbomicrolite

(Pb,◻)2Ta 2O6(◻,O,OH)

kubisch : m3m : Fd3m

4.DH.15

Oxycalciopyrochlore

Ca2Nb2O6O

4.DH.15

Fluorcalciomicrolite

(Ca,Na)2Ta2(O,OH)6F

kubisch : m3m : Fd3m

4.DH.15

Hydroxykenoelsmoreite

(☐,Pb)2(W,Fe3+,Al)2(O,OH)6(OH)

trigonal : 3 : R3

4.DH.15

Hydroxykenomicrolite

(◻,Na,Sb3+)2Ta2O6(OH)

kubisch : m3m : Fd3m

4.DH.15

Hydroxykenopyrochlore

(☐,Ce,Ba)2(Nb,Ti)2O6(OH,F)

kubisch : m3m : Fd3m

4.DH.15

Fluorcalciopyrochlore

(Ca,Na)2(Nb,Ti)2O6F

kubisch : m3m : Fd3m

4.DH.15

Hydroxynatropyrochlore

(Na,Сa,Ce)2Nb2O6(OH)

kubisch : m3m : Fd3m

4.DH.15

Hydroxycalciomicrolite

Ca1.5Ta2O6(OH)

kubisch : 432 : P4332

4.DH.15

Hydroxyplumbopyrochlore

(Pb1.50.5)Nb2O6(OH)

kubisch : m3m : Fd3m

4.DH.15

Hydroxycalciopyrochlore

(Ca,Na,U,☐)2(Nb,Ti)2O6(OH)

kubisch : m3m : Fd3m

4.DH.15

Fluorcalcioroméite

(Ca,Na)2Sb5+2O6(F,OH)

kubisch : m3m : Fd3m

4.DH.15d

Related minerals "Hoelzel Classification" [Mineral | Chemical formula : Crystal system : Class (H-M) | Space Group | Indenture number]

Hydroxycalciopyrochlore

(Ca,Na,U,☐)2(Nb,Ti)2O6(OH)

kubisch : m3m : Fd3m

4.CH.110

Hydroxymanganopyrochlore

(Mn,Th,Na,Ca,REE)2(Nb,Ti)2O6(OH)

kubisch : m3m : Fd3m

4.CH.119

Fluorcalciopyrochlore

(Ca,Na)2(Nb,Ti)2O6F

kubisch : m3m : Fd3m

4.CH.120

Oxycalciopyrochlore

Ca2Nb2O6O

4.CH.140

'Stibiobetafite' (Var.v. Pyrochlore group)

(Sb3+,Ca)2(Ti,Nb,Ta)2(O,OH)7

kubisch : m3m : Fd3m

4.CH.141

Related minerals "Dana 8. Classification" [Mineral | Chemical formula : Crystal system : Class (H-M) | Space Group | Indenture number]

'Pyrochlore'

08.02.01.01

Hydropyrochlore

(H2O,☐)2Nb2(O,OH)6(H2O)

kubisch : m3m : Fd3m

08.02.01.02

'Bariopyrochlore' (Var.v. Pyrochlore supergroup)

(Ba,Sr)(Nb,Ti)2(O,OH)7

kubisch : m3m : Fd3m

08.02.01.03

'Yttropyrochlore-(Y)' (Var.v. Pyrochlore group)

(Y,Na,Ca,U)1-2(Nb,Ta,Ti)2(O,OH)7

08.02.01.04

'Ceriopyrochlore-(Ce)' (Var.v. Pyrochlore supergroup)

(Ca,Ce,Y,Na)2(Nb,Ta)2(O,OH,F)7

kubisch : m3m : Fd3m

08.02.01.05

'Plumbopyrochlore' (Var.v. Pyrochlore group)

(Pb,Y,U,Ca)2-xNb2O6(OH)

kubisch : m3m : Fd3m

08.02.01.06

'Uranopyrochlore' (Var.v. Pyrochlore supergroup)

(Ca,U,Na,Ce)2(Nb,Ta)2(O,OH,F)7

kubisch : m3m : Fd3m

08.02.01.07

'Bismutopyrochlore' (Var.v. Pyrochlore supergroup)

(Bi,U,Ca,Pb)1+x(Nb,Ta)2O6(OH)·nH2O

kubisch : m3m : Fd3m

08.02.01.09

'Bariomicrolite'

Ba(Ta,Nb)2(O,OH)7

kubisch : m3m : Fd3m

08.02.02.02

'Plumbomicrolite' (Var.v. Microlite group)

(Pb,Na,Ca)2(Ta,Nb)2(O,OH)7

kubisch : m3m : Fd3m

08.02.02.03

'Uranmicrolite' (Var.v. Microlite group)

(Ca,U)2(Ta,Nb)2O6(OH,F)

kubisch : m3m : Fd3m

08.02.02.04

'Bismutomicrolite'

(Bi,Ca)(Ta,Nb)2O6(OH)

kubisch : m3m : Fd3m

08.02.02.05

'Stannomicrolite' (Var.v. Microlite group)

(Sn2+,Fe2+)(Ta,Nb,Sn4+)2(O,OH)7

kubisch : m3m : Fd3m

08.02.02.06

'Stibiomicrolite' (Var.v. Microlite group)

(Sb,Ca,Na)2(Ta,Nb)2(O,OH)7

kubisch : m3m : Fd3m

08.02.02.07

'Betafite group'

08.02.03.01

'Yttrobetafite-(Y)' (Var.v. Pyrochlore supergroup)

(Y,U,Ce)2(Ti,Nb,Ta)2O6(OH)

amorph

08.02.03.02

'Plumbobetafite' (Var.v. Pyrochlore supergroup)

(Pb,U,Ca)(Ti,Nb)2O6(OH,F)

kubisch : m3m : Fd3m

08.02.03.03

'Stibiobetafite' (Var.v. Pyrochlore group)

(Sb3+,Ca)2(Ti,Nb,Ta)2(O,OH)7

kubisch : m3m : Fd3m

08.02.03.04

'Calciobetafite' (Var.v. Pyrochlore supergroup)

Ca2(Ti,Nb)2(O,OH)7

kubisch : m3m : Fd3m

08.02.03.05

'Cesstibtantite' (Var.v. Pyrochlore supergroup)

(Cs,Na)SbTa4O12

kubisch : m3m : Fd3m

08.02.04.01

'Natrobistantite' (Var.v. Microlite group)

(Na,Cs)Bi(Ta,Nb,Sb)4O12

08.02.04.02

Zircosulfate

Zr(SO4)2·4H2O

orthorhombisch : mmm : Fddd

08.02.05.01

Orthobrannerite

U4+U6+Ti4O12(OH)2

orthorhombisch : 222 : P2122

08.02.07.01

'Parabariomicrolite ' (Pol.v. Hydrokenomicrolite)

BaTa4O10(OH)2·2H2O

08.02.08.01

Alternative Name

Spanish

Stibiobetafita

CNMNC (IMA)-Number

IMA 1978-052

Automatic Links to external internet sources (Responsibility is with the operator)

German pages

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